[(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

نویسندگان

  • Primjira P. Tadbuppa
  • Edward R. T. Tiekink
چکیده

The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π.

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[(Z)-O-Isopropyl N-phenyl­thio­car­bam­ato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯O inter-actions.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010